How to Label and Mark Hazardous Materials Correctly

Jan 7 / Erin Ford

When handling or shipping hazardous materials, proper labeling and marking are essential for safety and compliance. These identifiers communicate crucial information about the materials being transported—helping prevent accidents, ensuring proper handling, and guiding emergency responders if something goes wrong.

Understanding how to correctly label and mark hazardous materials isn’t just a regulatory requirement—it’s a key part of keeping people, property, and the environment safe.

Why Proper Labeling Matters

Labels and markings provide a universal system for recognizing hazards. They make sure anyone who comes in contact with the materials—whether in a warehouse, in transit, or at a job site—knows exactly what they’re dealing with.

Correct labeling helps:

  • Prevent accidents and misunderstandings during handling, transport, and storage.
  • Meet DOT and PHMSA requirements outlined in 49 CFR Parts 172–180.
  • Protect your organization from fines, shipping delays, and safety incidents.

Labels vs. Markings: What’s the Difference?


Although the terms are often used together, labels and markings have distinct roles:

  • Labels are diamond-shaped hazard symbols, typically 4 x 4 inches, that indicate a material’s hazard class—such as flammable, corrosive, or toxic.
  • Markings provide written details, including the UN identification number (e.g., UN1203 for gasoline), the proper shipping name, and any special handling instructions like “Inhalation Hazard” or “Marine Pollutant.”


Both must be visible, durable, and legible, remaining intact through normal transportation and handling.

Your Clearinghouse record follows you everywhere. That’s good news for safety—but it means drivers must take testing requirements seriously.

Key Requirements for Labeling and Marking

When preparing hazardous materials for shipment:

  1. Review the Shipping Papers
    Ensure the proper shipping name, hazard class, and UN number are listed correctly. These determine the exact labels and markings required.
  2. Apply the Correct Labels
    • Use the appropriate primary hazard label and, if needed, a subsidiary hazard label.
    • Place labels on the same surface and near the shipping name marking.
    • Make sure labels are flat, unobstructed, and securely affixed.
  3. Use Proper Markings
    • Include the correct UN/NA identification number and the shipper or consignee name and address.
    • Add any required additional wording (e.g., “Limited Quantity,” “Inhalation Hazard,” etc.).
    • Ensure markings are durable and resistant to weather, abrasion, and chemicals.
  4. Inspect Regularly
    Before shipment and during handling, check that all labels and markings remain legible and in good condition. Damaged or missing labels must be replaced immediately.

Common Mistakes to Avoid

  • Using incorrect or outdated hazard labels.
  • Applying labels to curved or uneven surfaces that make them hard to read.
  • Omitting required subsidiary hazard labels.
  • Forgetting to ensure that the UN number on the package matches the shipping paper.

Staying Compliant and Safe

  • Keep a copy of 49 CFR 172 Subparts D–F available for reference.
  • Schedule regular hazardous materials training for all employees involved in packaging, labeling, or shipping hazmat.
  • Choose durable, weather-resistant materials for outdoor or long-distance shipments.
  • When uncertain, contact your hazardous materials safety officer or the PHMSA Hazardous Materials Information Center for clarification.

Final Thoughts

Proper labeling and marking of hazardous materials are fundamental steps in maintaining safety throughout the supply chain. They ensure that everyone—from handlers to inspectors to emergency responders—has the information they need to stay safe.

Taking the time to verify labels, markings, and documentation before shipment isn’t just about compliance—it’s about responsibility. When done right, it protects your workers, your community, and your business.